On a special Master Distiller Tournament, five champion outlaw distillers battle it out in a backwoods battle royale. Amanda, Richard, Kelly, Tater and Mike pit their ingenuity against each other in a series of sudden-elimination challenges.

Moonshine has an Irish forefather, a high-proof spirit called Poitin, still outlawed in Northern Ireland. For this challenge, three skilled distillers bring their own ingredients and rebel spirit, but only one will be crowned Master Distiller.

Flavored whisky is a billion-dollar market on the legal side, but when Tickle hears the challenge, he crashes the party as an outlaw contender. Facing two skilled distillers, each must craft a recipe from scratch for a chance to be named Master Distiller.

Rare and illegal, wild ginseng can command thousands of dollars per pound; for three aspiring distillers, a run of ginseng liquor can mean hitting the high-dollar jackpot and a chance to be named Master Distiller.

Tea and liquor –– they're two beverages Americans will fight a rebellion for; Mark, Digger, and Tim judge as three distillers compete to turn America's duo of hard-won drinks into one top-selling spirit.

Distillers compete to run the best jar of America's original outlaw spirit.

A base recipe invented centuries ago spawned today's American moonshines and bourbons; three distillers will start with the same heritage corn and battle for their own liquor legacy and a chance to be named Master Distiller.

Three expert distillers forage free raw ingredients from nature and compete to turn them into tasty, high-proof spirits. But with backwoods legends Mark, Digger and Tim at the judging table, the price of failure far exceeds the low cost of entry.